Showing posts with label Chemical formulae and chemical equations. Show all posts
Showing posts with label Chemical formulae and chemical equations. Show all posts

Thursday, 28 May 2015

1.27 carry out mole calculations using volumes and molar concentrations.

CALCULATING MOLES:

- To calculate moles using volumes and molar concentrations, you simply do:
- Moles = Concentration x Volume.

An example from (http://www.docbrown.info/page04/4_73calcs11msc.htm)
What mass of sodium hydroxide (NaOH) is needed to make up 500 cm3 (0.500 dm3) of a 0.500 mol dm-3 (0.5M) solution? [Ar's: Na = 23, O = 16, H = 1]
- 1 mole of NaOH = 23 + 16 + 1 = 40g
- molarity = moles / volume, so mol needed = molarity x volume in dm3
500 cm3 = 500/1000 = 0.50 dm3
- mol NaOH needed = 0.500 x 0.500 = 0.250 mol NaOH
- therefore mass = mol x formula mass
- = 0.25 x 40 = 10g NaOH required 

1.26 calculate percentage yield

CALCULATING PERCENTAGE YIELD:

- To calculate percentage yield you do:
- Percentage yield = Actual yield (grams) / Theoretical Yield (grams) x 100
- Always between 0% and 100%, never above.

1.25 calculate reacting masses using experimental data and chemical equations

CALCULATING REACTING MASSES:

- 1. Write out the balanced equation.
- 2. For the bits you need, given in the question, write their relative formula mass and multiply them by the balancing numbers (numbers in front of the formulae).
- 3. The next bit is confusing, if the ratio was 1X : 2Y, you would divide 1X by 1 and 2Y by 1 to get how much 1 gram of X to reacts to make ... grams of Y.

To see a better explanation with examples goto: http://www.docbrown.info/page04/4_73calcs14other5.htm

1.24 calculate empirical and molecular formulae from experimental data

EMPIRICAL FORMULA:

- It is the smallest whole number ratio of atoms in a compound.

- 1. Write all the elements in compound.
- 2. Write their masses / percentages from the question.
- 3. Divide them by relative atomic mass.
- 4. Multiply or divide each number to get a whole number.
- 5. Obtain ratio in simplest form and write into formulae.

MOLECULAR FORMULAE:

- It is the exact value of atoms of each element in a single molecule.
- They are whole number multiples of empirical formulae.

- 1. Find the mass of empirical formulae.
- 2. That gives you how many empirical units are in the molecule.
- 3. Therefore you do the given empirical formulae x empirical units.

Wednesday, 27 May 2015

1.23 understand how the formulae of simple compounds can be obtained experimentally, including metal oxides, water and salts containing water of crystallisation

FORMULAE:

- 1. Find the mass of the multiple compounds.
- 2. Calculate the moles of water lost. That is mass / Mr.
- 3. Calculate the moles of anhydrous salt made. That is mass / Mr.
- 4. Work out ratio of anhydrous and water. Must be a whole number, e.g. if you get 0.02 moles of X and 0.01 moles of Y the ratio would be 2X : 1Y (since 0.02 / 0.01)

Another example: (thank you - http://www.docbrown.info/page04/4_73calcs14other4.htm)
Calculate the % of water in hydrated magnesium sulphate MgSO4.7H2O salt crystals
- Relative atomic masses: Mg = 24, S = 32, O = 16 and H = 1
- relative formula mass = 24 + 32 + (4 x 16) + [7 x (1 + 1 + 16)] = 246
- 7 x 18 = 126 is the mass of water
- so % water = 126 x 100 / 246 = 51.2%

1.22 use the state symbols (s), (l), (g) and (aq) in chemical equations to represent solids, liquids, gases and aqueous solutions respectively

STATE SYMBOLS:

- They tell you the physical state of what the reactants and products are.
- (s) is solid.
- (l) is liquid.
- (g) is gas.
- (aq) is aqueous - which means that it has been dissolved in water.

1.21 write word equations and balanced chemical equations to represent the reactions studied in this specification

BALANCED EQUATIONS:

- A chemical equation can be used to show reactants to products in the form of word or symbol equations.

- Symbol equations must be balanced; there must be equal number of atoms on each side. To do this you add numbers in front of the formulae.
E.g:
copper + oxygen --> copper(II) oxide
Cu + O2 --> CuO
- However this isn't balanced so you add numbers.
- There are 2 oxygens so you need to make CuO x2 ; it becomes 2CuO. This still isn't balanced as we have Cu + O2 --> 2CuO. This now tells us that there are 2 coppers so we simply do Cu x2 to make 2Cu.
- The final correct equation is 2Cu + O2 --> 2CuO